反應工程(英文) | 做自己 - 2024年11月
反應工程(英文)
本書立足於傳授反應工程基本原理,並與工程實踐相結合;服務於高等院校化工類專業的廣大師生,工程公司的設計人員以及生產企業的工程技術人員。
內容編排採用了循序漸進的方式。首先,分別介紹氣固相催化反應的本征和宏觀動力學,推導了間歇反應器、全混流反應器和活塞流反應器三種理想反應器的設計方程;在連續反應器流動模型的基礎之上,建立起固定床、流化床和流固相非催化反應動力學及真實反應器的模型;同時,將反應器的間歇與連續、恒容與變容、絕熱與換熱的各種操作方式貫穿其中,並簡要介紹了操作過程的多定態和定態穩定性;最後,針對生化、聚合及電化學反應工程的特點,分章加以介紹。全書共計13章,前7章可用作本科生教材,後6章可作為研究生的學習內容。
全書文字敘述精煉、模型推導詳盡、知識內容完整,並結合大量的例題和習題,深入淺出地傳授反應工程知識,培養讀者建立反應器模型和與之相關的工程設計能力。
List of Contributors
Preface
1. Introduction
1.1 Chemical Reaction Engineering
1.2 Conversion and Yield of Chemical Reactions
1.2.1 Extent of Reaction
1.2.2 Conversion
1.2.3 Yield and Selectivity
1.3 Classifications of Chemical Reactors
1.4 Operation Modes of Chemical Reactors
1.5 Models in Reactor Design
1.6 Scale-Up of Industrial Reactors
Further Reading
Problems
2. Fundamentals of Reaction Kinetics
2.1 Reaction Rate
2.2 Reaction Rate Equations
2.3 Effect of Temperature on Reaction Rate
2.4 Multiple Reactions
2.4.1 Consumption Rate and Formation Rate
2.4.2 Basic Types of Multiple Reactions
2.4.3 Reaction Network
2.5 Transformation and Integration of Reaction Rate Equations
2.5.1 Single Reaction
2.5.2 Multiple Reactions
2.6 Heterogeneous Catalysis and Adsorption
2.6.1 Heterogeneous Catalysis
2.6.2 Adsorption and Desorption
2.7 Kinetics of Heterogeneous Catalytic Reactions
2.7.1 Steady-State Approximation and Rate-Determining Step
2.7.2 Rate Equations of Heterogeneous Catalytic Reactions
2.8 Determination of Kinetic Parameters
2.8.1 Integration Method
2.8.2 Differential Method
2.9 Procedure for Developing Reaction Rate Equation
Further Reading
Problems
3. Tank Reactor
3.1 Mass Balance for Tank Reactor
3.2 Design of Isothermal Batch Tank Reactor(Single Reaction)
3.2.1 Calculation of Reaction Time and Reaction Volume
3.2.2 Optimal Reaction Time
3.3 Design of Isothermal Batch Tank Reactor (Multiple Reactions)
3.3.1 Parallel Reactions
3.3.2 Consecutive Reactions
3.4 Reactor Volume for Continuous Tank Reactor (CSTR)
3.5 CSTR in Series and Parallel
3.5.1 Overview
3.5.2 Calculations for Multiple Reactors in Series
3.5.3 Optimal Reaction Volume Ratio for CSTR in Series